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Friday, November 8, 2013

Photochemistry

Photophysical parameters and optical maser activity of 3(4-Dimethylamino-phenyl)-1-(2, 5-dimethyl-thiophen-3-yl) - propenone (DDTP): A new potential laser soil Samy A. El-Daly *1 , Abdullah M. Asiri1,2 , Abdullah Y. Obeid1 Salman A. Khan1 Khalid.A.Alamry1, Mahmoud.A.Hussien 1, Abdullah G.Al-Sehemi 3 1Chemistry Department, skill of Science, King Abdulaziz University, P.O. incase seat 80203, Jeddah 21589, Saudi-Arabian Arabia 2 Center of Excellence for good Materials Research, King Abdulaziz University, Jeddah 21589, P.O. Box 80203, Saudi Arabia 3 Chemistry Department, Faculty of Science, King Khalid University,Abha,Saudi Arabia revoke: The Photophysical parameters such as singlet absorption, seawallar absorptivity, oscillator strength, dipole antenna moment, fluorescence spectra and fluorescence quantum retort of DDTP were measu exit in different dissolvers. DDTP dye exhibits red put forward in both absorption and emanation spectra as solvent polarity increases, indicating that the dipole moment of DDTP dye is higher in phrenetic state than that in the intellect state. The density structural calculation were used to obtain the foundation state and excited state dipole moments for it has proven to be suitable for calculative electronic excitation energy.
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A pellucid solid of DDTP gives excimer similar dismissal at 575 nm. The absorption and sack spectra of DDTP have been investigated in organized media of aqueous micellar solution. The critical micelle engrossment (CMC) of sodium dodecyl sulfate (SDS), cetyltrimethyl ammonium bromide ( CTAB) and triton X-100 (TX-100) ar determin! ed employ DDTP dye. Dye solution ca 1 x 10-3 mol dm-3 in dimethyl sulfoxide (DMSO) gives laser emission in the range 490-560 nm with emission maximum at 520 nm upon pumping by newton laser (337.1). The gain coefficient (?) and emission mollycoddle section ?e at maximum laser emission are as well as determined. Keywords; Chalcone, laser dye, return of solvents, fluorescence quantum yield, hydrogen bonding,...If you want to get a full essay, site it on our website: OrderCustomPaper.com

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